Chemistry Letters · 1998 · 64 citations · 12 references
Natural SciencesChemistryMaterials ScienceMolecular RecognitionOrganic ChemistrySupramolecular ChemistryIntermolecular ForcesIntermolecular InteractionsSupramolecular MaterialsSupramolecular RecognitionFullerenesMolecular Inclusion ComplexesPolymer Inclusion ComplexesSingle-crystal DiffractionSingle-crystal X-ray DiffractionSupramolecular Coordination ComplexesSupramolecular Inclusion Complexes
Abstract CTV derivatives with aromatic pendants were synthesized and their inclusion abilities for C60 and C70 were examined by UV spectroscopy. CTV derivative with three N-methylpyrrole pendants showed the highest association constant for C60 (48000 dm3mol−1 in benzene). The structure of inclusion complex for C60 with CTV derivative which has six benzoyl pendants has been determined by single-crystal X-ray diffraction.
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