Annual Review of Physical Chemistry · 2012 · 230 citations · 72 references
Natural SciencesChemistryPhysicsMolecular PhysicsNuclear ChemistrySpectroscopyMagnetic Resonance SpectroscopyNuclear SpinRelaxation MechanismsSolution-state Magnetic ResonanceSpin DynamicsHyperpolarized Nuclear Magnetic ResonanceMagnetic Resonance Relaxation TimesMolecular Geometry DeterminationMolecular Relaxation ProcessesNuclear Magnetic Resonance RelaxationNuclear Magnetic Resonance SpectroscopyNuclear Spin DynamicsSolution-state Nuclear Magnetic Resonance Spectroscopy
Nuclear singlet states may have lifetimes that are much longer than the conventional relaxation time of nuclear spin magnetization. This review covers how these states may be generated, observed, and exploited in solution nuclear magnetic resonance (NMR). Potential applications include the study of slow molecular processes, the elucidation of molecular geometry, and the transport of hyperpolarized nuclear spin order.
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Nuclear Double Resonance in the Rotating Frame
S. R. Hartmann, E. L. Hahn · Physical Review · 1962 · 2.2K citations