Angewandte Chemie International Edition · 2002 · 94 citations · 23 references
Natural SciencesChemical EngineeringChemistryCatalysisIndustrial ChemistryOrganic ChemistryHeterocycle SynthesisHeterocyclic ChemistryOrganic SynthesisRetrosynthetic AnalysisSafer Chemical SynthesisCatalyst ActivationHeterocycle FunctionalizationMetathesis CatalysisOlefin MetathesisOlefin Metathesis CatalysisStereoselective OxidationStereospecific Reaction Design
Stereoselective and chemoselective olefin cross metathesis can be viewed as a highly selective and efficient set of reactions that provide the same products as would selective CH activation and allylic oxidation (see scheme for an example). More active catalyst systems will provide an efficient process to functionalized products from readily available olefins. Cy=cyclohexyl.
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Remarkably Selective Iridium Catalysts for the Elaboration of Aromatic C-H Bonds
Jian-Yang Cho, Man Kin Tse, Daniel Holmes et al. · Science · 2002 · 1.1K citations