Chemical Communications · 2008 · 56 citations · 38 references
Natural SciencesChemical EngineeringChemistryCatalysisOrganometallic ChemistryCatalyst PreparationCatalyst SynthesisCatalytic MechanismsAsymmetric BiocatalysisAsymmetric CatalysisAsymmetric Catalyst DesignAsymmetric SynthesisChiral Catalyst DesignEnantioselective CatalysisEnantioselective Catalyst DesignEnantioselective Synthesis
A facile method for the preparation of highly active and enantioselective yttrium precatalysts for asymmetric hydroamination of gem-disubstituted aminoalkenes, from the combination of YCl(3) or YCl(3)(THF)(3.5) with ligand (R)- and n-BuLi is described.
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Organolanthanide-Catalyzed Hydroamination
Sukwon Hong, Tobin J. Marks · Accounts of Chemical Research · 2004 · 1K citations