Concepedia

Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids

Chenghong Huang, Theresa Liang, Shinji Harada, Eunsung Lee, Tobias Ritter

Journal of the American Chemical Society · 2011 · 213 citations · 58 references

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Concepts

Abstract

A silver-mediated cross-coupling of trifluoromethoxide with aryl stannanes and arylboronic acids to give aryl trifluoromethyl ethers is reported. This is the first report of a transition-metal-mediated C(aryl)-OCF(3) bond formation.

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