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Spirocycloisomerization of Tethered Alkylidene Glycocyamidines: Synthesis of a Base Template Common to the Palau'amine Family of Alkaloids
79
Citations
20
References
2004
Year
Facile SpirocyclizationBioorganic ChemistryBiochemistryCore Model SystemNatural SciencesMedicineOrganic ChemistryBase Template CommonPalau'amine FamilyChemistryTethered Alkylidene GlycocyamidinesPharmacologyTethered Bisalkylidene 1Synthetic ChemistryEnantioselective SynthesisDrug DiscoveryNatural Product Synthesis
The facile spirocyclization of tethered bisalkylidene 1 suggests a general synthetic strategy for preparing alkaloids of the palau'amine family. The development and characteristics of this core model system are discussed.
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