C-Glycosidation with Silylacetylenes to D-glucals

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Chemical Engineering, Catalytic Substitutions, Engineering +8

A Convenient Synthesis of Ethynylarenes and Diethynylarenes

S. Takahashi, Y. Kuroyama, Kenkichi Sonogashira et al. · Synthesis · 1980 · 1.1K citations

Alkene Metathesis, Organic Chemistry, Convenient Synthesis +3

Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride

Akíra Hosomi, Hideki Sakurai · Tetrahedron Letters · 1976 · 438 citations

Chemical Engineering, Engineering, δ-Unsaturated Alcohols +6

Synthesis of C-glycosyl compounds from 3,4,6-tri-O-acetyl-1,5-anhydro-d-arabino-hex-1-enitol and allyltrimethylsilane and bis(trimethylsilyl)acetylene

Yoshiyasu Ichikawa, Minoru Isobe, Masato Konobe et al. · Carbohydrate Research · 1987 · 93 citations

Engineering, Glycobiology, C-glycosyl Compounds +7

Stereocontrolled total synthesis of (-)-maytansinol

Masato Kitamura, Minoru Isobe, Yoshiyasu Ichikawa et al. · Journal of the American Chemical Society · 1984 · 91 citations

Chemical Measurement, Chemical Analysis, Altmetric Attention Score +10