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Structural Revisions of Some Non-Adjacent Bis-Tetrahydrofuran Annonaceous Acetogenins
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1993
Year
Medicinal ChemistryBioorganic ChemistryHeterocyclicBiochemistryNatural SciencesAnnonins ViiiMolecular BiologyRelative StereochemistriesOrganic ChemistryStereoselective SynthesisChemistryHeterocycle ChemistryNatural Product SynthesisStructural RevisionsSynthetic ChemistryEnantioselective SynthesisCosy Spectra
The relative stereochemistries of bullatalicin [1] and bullatalicinone [2] were partially reassigned based on COSY and relayed COSY spectra. The structures of annonins VIII [3], IV [4], and XVI [5] were revised and concluded as bullatalicin [1], bullatanocin [6], and squamostatin A [7], respectively.