Concepedia

Allene Cross-Metathesis: Synthesis of 1,3-Disubstituted Allenes

Mahmood Ahmed, Thomas Arnauld, Anthony G. M. Barrett, D. Christopher Braddock, Kevin Flack, Panayiotis A. Procopiou

Organic Letters · 2000 · 79 citations · 10 references

DOI

Concepts

Abstract

[reaction: see text] Grubbs catalyst, Cl2(Cy3P)2Ru=CHPh, was found to catalyze the cross-metathesis of monosubstituted allenes to 1,3-disubstituted allenes in varying yields.

References

10

Recent advances in olefin metathesis and its application in organic synthesis

Robert H. Grubbs, Sukbok Chang · Tetrahedron · 1998 · 2.1K citations

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Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins

Richard R. Schrock, John S. Murdzek, Gui C. Bazan et al. · Journal of the American Chemical Society · 1990 · 1.1K citations

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Olefin Metathesis-Active Ruthenium Complexes Bearing a Nucleophilic Carbene Ligand

Jinkun Huang, Edwin D. Stevens, Steven P. Nolan et al. · Journal of the American Chemical Society · 1999 · 999 citations

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Well-Defined Ruthenium Olefin Metathesis Catalysts:  Mechanism and Activity

Eric L. Dias, SonBinh T. Nguyen, Robert H. Grubbs · Journal of the American Chemical Society · 1997 · 662 citations

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The first co-ordinatively unsaturated Group 8 allenylidene complexes: insights into Grubbs’ vs. Dixneuf–Fürstner olefin metathesis catalysts

Karsten J. Harlow, Anthony F. Hill, James D. E. T. Wilton‐Ely · Journal of the Chemical Society Dalton Transactions · 1999 · 123 citations

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