Temperature dependence of the mean square relative displacements of nearest-neighbour atoms derived from EXAFS spectra

Abstract

An investigation of the dependence on temperature of the extended X-ray absorption fine structure (EXAFS) above the K-edges of Cu and Co in the metals and above the K-edges of Rb and Sr in the compounds RbCl, SrS, SrF 2 and SrCl 2 has been performed. For Cu, Co, RbCl and SrS, the values of the correlated mean square relative displacements of nearest-neighbour atoms derived from EXAFS spectra show a good agreement with those calculated from a Debye model. The experimental data obtained are also compared with available data for mean square displacements of the individual atoms calculated from more-refined lattice vibrational models and with Debye-Waller factors used in X-ray diffraction experiments.