Photoswitched and Functionalized Oligothiophenes: Synthesis and Photochemical and Electrochemical Properties

Abstract

Abstract The extended dithienylethene compounds 1–3 have been synthesized. They undergo photochromic and electrochemical changes by photoinduced interconversion between open and closed forms of type A and B . In addition, both forms of the N ‐methylated derivatives 1b and 2b have absorption bands in which excitation results in very large differences in fluorescence between the two forms with very little effect on the opening/closing state, a feature of interest for optical memory data systems. The compounds 2 and 3 contain six and eight conjugated thiophene units in the closed forms, respectively, and thus represent oligothiophenes endowed with a photoactivated switch; they are of special interest in this respect in view of the potential use of switched oligothiophenes in molecular electronic devices.