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Synthesis and Structure of [C<sub>2</sub>H<sub>10</sub>N<sub>2</sub>][B<sub>5</sub>O<sub>8</sub>(OH)]: A Nonmetal Pentaborate with Nonlinear Optical Properties
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Citations
25
References
2007
Year
Crystal StructureOptical MaterialsEngineeringSolid-state ChemistryChemistryInorganic MaterialOptical PropertiesNonmetal PentaborateYag LaserMaterials SciencePhotonicsInorganic ChemistryNon-linear OpticSecond-harmonic GenerationCrystallographyCrystal Structure DesignNonlinear Optical PropertiesOptical PhysicX-ray DiffractionApplied Physics
A nonmetal pentaborate [C2H10N2][B5O8(OH)] (I) was synthesized by a solvothermal method at 150 °C and characterized by elemental analysis, IR, thermogravimetric analysis, and X-ray diffraction. The structure of I was determined by a single-crystal technique. It crystallizes in the monoclinic system with space group Cc, a = 6.7085 (13) Å, b = 11.437(2) Å, c = 12.530(3) Å, and β = 95.41(3)°. Powder second-harmonic generation (SHG) efficiency measurements with Nd:YAG laser (1064 nm) radiation show that [C2H10N2][B5O8(OH)] has a SHG efficiency approximately 1.2 times of that of potassium dihydrogen phosphate (KDP).
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