Ultracold-molecule production by laser-cooled atom photoassociation

Abstract

We propose a method for copiously producing ultracold ground electronic-state molecules by two-photon absorption to a Rydberg molecular level (that spontaneously radiates to the ground molecular state) during collisions of ultracold atoms in a laser trap. Using the ${\mathrm{Na}}_{2}$ molecule as an example, the sequential two-photon absorption is via an intermediate high-lying vibrational level of the excited ${1}_{\mathit{g}}$ state and results in the formation of a given vibrational level of a $^{1}\mathrm{\ensuremath{\Pi}}_{\mathit{u}}$ Rydberg molecular state. Realistic calculations demonstrating the validity of the method are presented.