Crystal Growth and Characterization of the Kondo Semimetal CeNiSn

Abstract

Several single crystals of CeNiSn and CeNi 0.95 T 0.05 Sn (T=Co and Cu) were grown and characterized by metallographic examination, electron-probe microanalysis and the measurements of resistivity, magnetoresistance, magnetic susceptibility and specific heat. Below 10 K, the semiconductor-like behavior found for dirty or substituted crystals is suppressed with decreasing impurities. For a crystal purified by the solid-state electrotransport technique, the resistivity along the orthorhombic a axis is metallic with the T 2 dependence, whereas those along the b and c axes increase below 3 K and pass through weak maxima at 0.8 K. These results suggest that the ground state of CeNiSn is not semiconducting but semimetallic with a pseudogap which closes along the a axis.