The Journal of Chemical Physics · 1982 · 76 citations · 12 references
Natural SciencesChemistryPhysicsMolecular PhysicsQuantum ChemistrySpectroscopyFluorescence SpectroscopyMolecular Excited StatesMolecular SpectroscopyOptical SpectroscopyPyrimidine ChemistryQuantum Interference EffectsResonance Interference EffectsTriplet-state Dynamics
We report here the observation of intramolecular quantum beats in the fluorescence of jet-cooled pyrimidine and pyrazine, which represents only the second example of interference effects exhibited by closely-spaced singlet–triplet molecular eigenstates of polyatomic molecules. (AIP)
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