Two Zeolite‐Type Frameworks in One Metal–Organic Framework with Zn ₂₄ @Zn ₁₀₄ Cube‐in‐Sodalite Architecture

Abstract

Two in one: A metal–organic framework obtained from three different inorganic building blocks (tetrameric Zn4O, trimeric Zn3OH, and monomeric Zn) posseses a nested cage-in-cage and framework-in-framework architecture (see picture). 24 Zn4O tetramers and eight Zn monomers form a sodalite cage into which a cubic cage made from eight Zn3(OH) trimers is nestled. Eight monomeric Zn2+ centers interconnect these two cages. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.