Concepedia

Copper(I) coordination compounds with closo-dodecaborate anion

V. N. Mustyatsa, Lyudmila V. Goeva, I.N. Polyakova, N. A. Votinova, К. Yu. Zhizhin

Russian Journal of Inorganic Chemistry · 2006 · 16 citations · 2 references

DOI

Concepts

Abstract

Copper(I) complexes with a closo-dodecaborate anion were synthesized: Cat[CuB12H12], where Cat = Cs+, Ph4P+, Ph4As+, or R x NH 4− + (R = Me, Et, Pr, or Bu; x = 3 or 4). The complexes were synthesized from the copper(II)-closo-dodecaborate-sulfur dioxide (sodium sulfite) system. The structure of [Cu2(NCCH3)4B12H12] was determined using X-ray crystallography.

References

2

Hexahydro-<i>closo</i>-hexaborate as a Ligand in Coordination Compounds:  Synthesis and Crystal Structure of (<i>n</i>-Bu<sub>4</sub>N)<sub>2</sub>[Cd(η<sup>3</sup>-B<sub>6</sub>H<sub>6</sub>)<sub>2</sub>]·2CH<sub>2</sub>Cl<sub>2</sub>

T. Schaper, W. Preetz · Inorganic Chemistry · 1998 · 22 citations

, , +15

Composition and Properties of Superconducting Materials Containing Rare Earths, V, and W

L. I. Ochertyanova, N.K. Bel'skii · Inorganic Materials · 2004 · 17 citations

, , +12