Concepedia

Diastereoselective Diels−Alder Reactions with an Allenyl-Containing Spiro-Amido Chiral Auxiliary

Jeff R. Henderson, J.P. Chesterman, Masood Parvez, Brian A. Keay

The Journal of Organic Chemistry · 2010 · 17 citations · 29 references

DOI

Concepts

Abstract

A novel allenyl-containing 1,3-spiro-amido alcohol auxiliary has been prepared and used in a variety of diastereoselective Diels-Alder reactions providing exclusively endo adducts with diastereomeric ratios ranging from 2:1 to >99:1.

References

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