Enantiopure Pseudo-<i>C</i>₃-Symmetric Titanium Alkoxide with Propeller-Like Chirality

Abstract

An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text].