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Preparation of titanium pentamethylcyclopentadienyl trialkyls and crystal structure of tribenzylpentamethylcyclopentadienyltitanium, showing some evidence of a CH2? Ti interaction
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1986
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Materials ScienceInorganic ChemistryTitanium Pentamethylcyclopentadienyl TrialkylsCrystal StructureEngineeringX-ray MethodsTrichloro AnalogueOrganic ChemistryTi InteractionOrganometallic CatalysisChemistryHeterocycle ChemistryDerivative (Chemistry)Inorganic SynthesisBiomolecular EngineeringCh2⋯ Ti InteractionInorganic Compound
Titanium pentamethylcyclopentadienyl trialkyls (η5-C5Me5)TiR3(R = Me, CH2SiMe3, C6F5, and CH2Ph) are easily obtained by conventional alkylation of the trichloro analogue; the structure of the tribenzyl derivative, determined by X-ray methods, shows some evidence of a CH2⋯ Ti interaction.