Fluorescence of Ti^3+ ions thermally diffused into sapphire

Abstract

The thermal diffusion of Ti(3+) ions into sapphire is demonstrated, and the spectroscopic characteristics of the locally doped region are presented. The spectral line shape, polarization dependence, and excited-state lifetime of indiffused Ti:sapphire are in excellent agreement with previously published data for high-quality, bulk-doped Ti:sapphire laser crystals. The observed diffusion rate at 1950 degrees C is of the order of D = 10(-14) m(2) s(-1). These results represent a significant step in the development of a versatile broadly tunable waveguide laser based on the Ti(3+):sapphire material system established for conventional bulk lasers.