Encapsulation of α-Tocopheryl Acetate into Zeolite Y for Textile Application

Abstract

A useful encapsulation methodology has been developed to fabricate α-tocopheryl acetate-zeolite Y microcapsules. These new microcapsules have been applied to obtain special textile polyamide fibers. The presence of α-tocopheryl acetate in both microcapsules and special fibers has been qualitatively and quantitatively determined using various techniques such as thermogravimetric analysis (TGA), infrared spectroscopy (FTIR), and high performance liquid chromatography (HPLC). Two different techniques to extract the α-tocopheryl acetate encapsulated in both microcapsules and special fibers have been compared: liquid−liquid extraction, that gives the best results under the studied conditions, and supercritical CO2 extraction, which is useful when there are mass transfer limitations as in the case of the special fibers. Mechanical properties of the fiber do not significantly change when they are fabricated with zeolite Y microcapsules. Finally, fabrics knitted with yarns of α-tocopheryl acetate-zeolite Y microcapsules state a significant presence of the additive after 100 washing machine cycles (30 °C, neutral soap).