physica status solidi (b) · 1968 · 10 citations · 2 references
Natural SciencesChemistryPhysicsPhysical ChemistrySpectroscopic AnalysisSpectroscopyAbsorption SpectroscopyAtomic SpectroscopyInorganic SpectroscopyMolecular Orbital TheoryMössbauer SpectroscopyResonance AbsorptionAntimony ChemistryBonding OrbitalsIsomer Shift AnalysisMössbauer Effect
Abstract The isomeric chemical shifts (IS) of the Mössbauer 37.2 keV γ‐line of the Sb 121 nucleus in organic compounds of antimony (type Ar 3 SbX 2 , Ar 4 SbX, and Ar 3 Sb) have been measured. The spectra of the resonance absorption are mainly found to be broadened single lines with appreciable asymmetry. The results obtained are interpreted on the basis of the semi‐empirical method of hybrid orbitals.
2
E. L. Muetterties, R. A. Schunn · Quarterly Reviews Chemical Society · 1966 · 269 citations