Publication | Closed Access
Novel Double-Stranded Chains vs Two-Layer Interwoven Sheets. Subtle Coligand Effects and Related Properties for [Co(Py<sub>2</sub>S)<sub>2</sub>X<sub>2</sub>]<i><sub>n</sub></i> (Py<sub>2</sub>S = 4,4‘-Dipyridyl Sulfide; X = NCS, Cl)
102
Citations
30
References
1998
Year
Materials ScienceInorganic ChemistryStructural DifferencesEngineeringLinear Chain CompoundApplied PhysicsMolecule-based MaterialMagic AngleCoordination PolymerChemistryColigand EffectsSupramolecular ChemistryMolecular ChemistryTwo-layer Interwoven SheetsNovel Double-stranded ChainsMetal Chain CompoundSubtle Coligand Effects
A study of striking structural differences in the magic angle of Py2S and coligand effects has been carried out. [Co(Py2S)2Cl2]n is the first integral two-layer interwoven sheet without any counterion or solvate whereas [Co(Py2S)2(NCS)2]n affords a double-stranded linear infinite structure. Thermal analyses of the complexes over the temperature range 25−430 °C show the significant thermal behaviors associated with the structure.
| Year | Citations | |
|---|---|---|
Page 1
Page 1