Reviews of Modern Physics · 2011 · 1.3K citations · 142 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsSolid State PhysicsSpectroscopyElectronic Band StructureStrongly Correlated Electron SystemsX-ray SpectroscopyInelastic ScatteringPhoton DetectionResonant Inelastic X-ray ScatteringResonant ScatteringStrongly Correlated Systems
Resonant inelastic X‑ray scattering has advanced rapidly in the past decade thanks to high‑brilliance synchrotron sources and sophisticated detectors, enabling direct measurement of elementary excitations in complex materials. This review surveys experimental and theoretical RIXS studies of the last decade, concentrating on low‑energy charge, spin, orbital, and lattice excitations, and outlines its future potential with emerging X‑ray laser sources. The authors describe the experimental fundamentals of RIXS, review recent theoretical developments and computational approaches for the dynamical response, and survey experimental data—especially on correlated transition‑metal systems—to illustrate its interpretive power.
In the past decade, Resonant Inelastic X-ray Scattering (RIXS) has made remarkable progress as a spectroscopic technique. This is a direct result of the availability of high-brilliance synchrotron X-ray radiation sources and of advanced photon detection instrumentation. The technique's unique capability to probe elementary excitations in complex materials by measuring their energy-, momentum-, and polarization-dependence has brought RIXS to the forefront of experimental photon science. We review both the experimental and theoretical RIXS investigations of the past decade, focusing on those determining the low-energy charge, spin, orbital and lattice excitations of solids. We present the fundamentals of RIXS as an experimental method and then review the theoretical state of affairs, its recent developments and discuss the different (approximate) methods to compute the dynamical RIXS response. The last decade's body of experimental RIXS data and its interpretation is surveyed, with an emphasis on RIXS studies of correlated electron systems, especially transition metal compounds. Finally, we discuss the promise that RIXS holds for the near future, particularly in view of the advent of x-ray laser photon sources.
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