Concepedia

ORBITAL COMPLEMENTARY AND COUNTERCOMPLEMENTARY EFFECTS IN SUPEREXCHANGE INTERACTION THROUGH HETEROBRIDGES IN BINUCLEAR COPPER(II) COMPLEXES

Yuzo Nishida, Masataka Takeuchi, Kazuhiro Takahashi, Sigeo Kida

Chemistry Letters · 1985 · 77 citations · 2 references

Concepts

Natural SciencesChemistryPhysicsCondensed Matter PhysicsQuantum ChemistryAntiferromagnetismCoordination ChemistryExchange InteractionsMetal-ligand BondingMolecular Orbital TheoryTransition Metal ComplexesElectronic Structure Of Metal ComplexesLigand Electronic EffectsMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesSuperexchangeSuperexchange Mechanism

Abstract

Abstract Low antiferromagnetism of μ-alkoxo-μ-carboxylatodicopper(II) complexes were reasonably explained in terms of the orbital countercomplementary effect based on Hoffmann’s theory for superexchange interaction.

References

2

Orbital interactions in metal dimer complexes

P. Jeffrey Hay, Jack C. Thibeault, Roald Hoffmann · Journal of the American Chemical Society · 1975 · 1.3K citations

Natural Sciences, Chemistry, Inorganic Chemistry +15

Copper(II) hemocyanin models

Vickie McKee, Jeffrey V. Dagdigian, Robert Bau et al. · Journal of the American Chemical Society · 1981 · 124 citations

Natural Sciences, Chemistry, Materials Science +8