Publication | Closed Access
Towards the Total Synthesis of Vibsanin E, 15‐<i>O</i>‐Methylcyclovibsanin B,3‐Hydroxyvibsanin E, Furanovibsanin A, and 3‐<i>O</i>‐Methylfuranovibsanin A
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Citations
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References
2006
Year
Bioorganic ChemistryEngineeringVibsanin EOrganic ChemistryMedicinal ChemistryDiversity Oriented SynthesisNatural Product BiosynthesisFuranovibsanin ADerivativesBiochemistryDiversity-oriented SynthesisTotal SynthesisO ‐Methylfuranovibsanin APharmacologyNatural Product SynthesisBiomolecular EngineeringNatural SciencesVibsanin‐type DiterpenesSynthetic Chemistry
Abstract Studies detailing synthetic approaches to a variety of biosynthetically related vibsanin‐type diterpenes (i.e. vibsanin E, 15‐ O ‐methylcyclovibsanin B, 3‐hydroxy‐vibsanin E, furanovibsanin A, and 3‐ O ‐methylfuranovibsanin A) are discussed. Biogenetically modelled approaches are coupled with an investigation of classical and modern six‐ to seven‐membered ring‐expansion protocols, which gain access to the central core of these natural products. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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