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Terminal Deoxy Hydroxyamino Sugars
26
Citations
9
References
1988
Year
Bioorganic ChemistryAldehyde DehydrogenaseBiochemistryAldo-keto ReductaseMedicineNatural SciencesRadical (Chemistry)GlycobiologySugar AldoximesOrganic ChemistryPolysaccharideDeoxygenationChemistryPharmacologyRedox BiologyAbstract ReductionEsr Spectra
Abstract Reduction of sugar aldoximes gave in good yield the corresponding terminal deoxy hydroxyamino sugars. These compounds were found to be reasonably stable (they could be kept for some weeks at 4° C). On standing in the air, these compounds in solution were spontaneously oxidized to the corresponding nitroxide free radicals whose ESR spectra gave useful structural information.
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