Publication | Closed Access
Electronic spectroscopy and excited state dynamics of the Ar⋅SH complex
39
Citations
20
References
1993
Year
EngineeringX̃ StatesLaser ApplicationsComputational ChemistryChemistryElectronic Excited StateSpectra-structure CorrelationPhotophysical PropertyMolecular SpectroscopyAr⋅sh ComplexPhysicsPhysical ChemistryQuantum ChemistryExcited State PropertyLaser PhotochemistryNatural SciencesSpectroscopyApplied PhysicsAr Complexation
The laser excitation spectrum à (0,00,vS′)−X̃ (0,00,0), has been observed for the Ar⋅SH complex. Rotational constants and bond lengths have been obtained for vibrational levels of the à and X̃ states. A remarkable lengthening of the à state natural lifetime is observed upon Ar complexation.
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