Enzymatic asymmetrisation of prochiral α,α-disubstituted-malonates and -1,3-propanediols: formal asymmetric syntheses of (−)-aphanorphine and (+)-eptazocine

Oxidation of long-chain and related alcohols to carbonyls by dimethyl sulfoxide "activated" by oxalyl chloride

Anthony J. Mancuso, Shui‐Lung Huang, Daniel Swern · The Journal of Organic Chemistry · 1978 · 1.6K citations

Natural Sciences, Chemistry, Analytical Chemistry +5

Horner-wadsworth-emmons reaction: Use of lithium chloride and an amine for base-sensitive compounds

Mary A. Blanchette, William Choy, Jeffery T. Davis et al. · Tetrahedron Letters · 1984 · 910 citations

Natural Sciences, Chemistry, Inorganic Chemistry +1

13. Researches on acetylenic compounds. Part I. The preparation of acetylenic ketones by oxidation of acetylenic carbinols and glycols

K. Bowden, I. M. Heilbron, E. R. H. Jones et al. · Journal of the Chemical Society (Resumed) · 1946 · 906 citations

Natural Sciences, Biochemistry, Chemistry +3

Methodology for the construction of quaternary carbon centers

Stephen F. Martin · Tetrahedron · 1980 · 379 citations

Natural Sciences, Earth Sciences, Geology +5

<b>The Reaction of Sodium Borohydride with Nickel Acetate in Aqueous Solution--A Convenient Synthesis of an Active Nickel Hydrogenation Catalyst of Low Isomerizing Tendency</b>

Charles A. Brown, Herbert C. Brown · Journal of the American Chemical Society · 1963 · 139 citations

Natural Sciences, Chemistry, Catalysis +10