Concepedia

Alkyl Transfer with Retention and Inversion of Configuration: Reexamination of a Putative [1s,4s] Sigmatropic Rearrangement

Saul Wolfe, Kiyull Yang, Noham Weinberg, Zheng Shi, Yih-Huang Hsieh, Rajendra D. Sharma, Stephen Ro, Chan-Kyung Kim

Chemistry - A European Journal · 1998 · 13 citations · 38 references

DOI

Concepts

Abstract

The reaction shown is not intramolecular Depending on R and the solvent, the product is formed either with net retention of configuration by a double inversion or with net inversion of configuration by two consecutive single inversions.

References

38

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Ab initio molecular orbital theory

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Catalytic asymmetric allylation of aldehydes

Gary E. Keck, Kenneth H. Tarbet, Leo S. Geraci · Journal of the American Chemical Society · 1993 · 509 citations

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The Relative Reaction Velocities of Isotopic Molecules

Jacob Bigeleisen · The Journal of Chemical Physics · 1949 · 381 citations

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