Angewandte Chemie International Edition in English · 1969 · 4.1K citations · 281 references
Natural SciencesPhysicsQuantum MechanicsTheoretical PhysicsMolecular Orbital TheoryMolecular SymmetrySpin-orbit CouplingSymmetry BreakingConservation Of Orbital SymmetryMolecular Orbital SymmetrySymmetries
The Conservation of Orbital Symmetry examines the principle of conservation of orbital symmetry and its use. The central content of the principle was that reactions occur readily when there is congruence between orbital symmetry characteristics of reactants and products, and only with difficulty when that congruence does not obtain-or to put it more succinctly, orbital symmetry is conserved in concerted reaction. This principle is expected to endure, whatever the language in which it may be couched, or whatever greater precision may be developed in its application and extension. The book ope
281
An Extended Hückel Theory. I. Hydrocarbons
Roald Hoffmann · The Journal of Chemical Physics · 1963 · 4.6K citations
Lajos Moln r · Nuclear Physics · 1966 · 2.5K citations