Zeitschrift für Naturforschung A · 1973 · 17 citations · 0 references
Natural SciencesChemistryPhysicsOrganic ChemistrySpectroscopic AnalysisSpectroscopyAb Initio MethodsChemical BondingMicrowave SpectroscopyMolecular BondingMolecular StructureMolecular SymmetryDipole Moment DeterminationMicrowave Absorption SpectraMolecular Geometry DeterminationMolecular Structure DeterminationNuclear Quadrupole CouplingQuadrupole InteractionQuadrupole SplittingStructural Elucidation From Spectra
The microwave spectra of three further isotopic species of methanesulfenyl chloride have been investigated. These results together with the results of investigations of isotopic species previously studied enable the calculation of a more accurate r 0 -structure. The r s -distance of the S-Cl bond has been determined. Orientation and direction of the dipole moment and the total quadrupole coupling tensor have also been obtained.