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Electronic structures of the group IVB tetramethyls by helium-(I) photoelectron spectroscopy
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1972
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EngineeringComputational ChemistryChemistryElectronic StructureSpectroscopic PropertySpectra-structure CorrelationElectron SpectroscopyPhysicsPhotochemistryObserved BandsAtomic PhysicsQuantum ChemistryPhotoelectron SpectroscopyNatural SciencesSpectroscopyCondensed Matter PhysicsLocalized Bond OrbitalsElectronic StructuresBasis SetGroup Ivb Tetramethyls
The helium-(I) photoelectron spectra of the species (CH3)4A, where A = C, Si, Ge, Sn and Pb, are reported. The observed bands are assigned using a simple molecular orbital model which employs localized bond orbitals as the basis set.