Highly stereoselectively cope rearrangements of enantiomerically pure, silylated syn-aldols

The overlap of two allyl radicals or a four-centered transition state in the cope rearrangement

W. von E. Doering, Wolfgang R. Roth · Tetrahedron · 1962 · 309 citations

Natural Sciences, Chemistry, Physical Chemistry +7

“P-2 nickel” catalyst with ethylenediamine, a novel system for highly stereospecific reduction of alkynes to cis-olefins

Charles A. Brown, V. K. AHUJA · Journal of the Chemical Society Chemical Communications · 1973 · 259 citations

Natural Sciences, Chemistry, Catalysis +14

(E)-3-(Trimethylsilyl)-2-propen-1-ol. An improved preparation

Scott E. Denmark, Todd K. Jones · The Journal of Organic Chemistry · 1982 · 190 citations

Natural Sciences, Chemistry, Analytical Chemistry +5

Highly enantioselective and diastereoselective Ireland-Claisen rearrangement of achiral allylic esters

E. J. Corey, Duck‐Hyung Lee · Journal of the American Chemical Society · 1991 · 150 citations

Natural Sciences, Chemistry, Mass Spectrometric Analysis +7

Aldol addition reactions of chiral crotonate imides

David A. Evans, Eric B. Sjogren, Javier Bartrolí et al. · Tetrahedron Letters · 1986 · 125 citations

Natural Sciences, Biochemistry, Chemistry +6