Concepedia

Sulfoxide-Mediated α-Arylation of Carbonyl Compounds

Xueliang Huang, Nuno Maulide

Journal of the American Chemical Society · 2011 · 168 citations · 62 references

DOI

Concepts

Abstract

A novel sulfoxide-mediated α-arylation of carbonyl compounds is reported. This reaction proceeds under very mild conditions at room temperature and does not require any transition-metal promoter or catalyst.

References

62

Diaryliodonium Salts: A Journey from Obscurity to Fame

Eleanor A. Merritt, Berit Olofsson · Angewandte Chemie International Edition · 2009 · 1.2K citations

, , +12

Catalytic Enantioselective Construction of All-Carbon Quaternary Stereocenters

Barry M. Trost, Chunhui Jiang · Synthesis · 2006 · 988 citations

, , +9

Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles

Darcy A. Culkin, John F. Hartwig · Accounts of Chemical Research · 2003 · 934 citations

, , +12

Catalytic asymmetric synthesis of all-carbon quaternary stereocenters

Christopher J. Douglas, Larry E. Overman · Proceedings of the National Academy of Sciences · 2004 · 828 citations · Full text

, , +12

Stereoselective Construction of Quaternary Stereocenters

Jens Christoffers, Angelika Baro · Advanced Synthesis & Catalysis · 2005 · 517 citations

, , +8