Angewandte Chemie International Edition in English · 1981 · 31 citations · 3 references
Natural SciencesChemistryCrystal StructureOrganic ChemistryPhysical ChemistryCluster ChemistryCluster CompoundsCoordination ChemistryCrystal ChemistryHeterocyclic ChemistryTransition Metal ComplexesCluster CarbonylsDirect ExchangeDouble ExchangeLigand Exchange ReactionsMetal-carbonyl ClustersMetal-metal Bonding In Carbonyl ClustersTransition Metal CarbonylsTransition Metal Clusters
A convenient route to the chemistry of heterotetrahedranes is provided by exchange reactions involving CH3CCo3(CO)9. The chiral cluster (1) was synthesized from the aforementioned cluster by a double metal exchange; (1) crystallized spontaneously, forming optically active crystals.
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Paul C. Steinhardt, Wayne L. Gladfelter, A. Dale Harley et al. · Inorganic Chemistry · 1980 · 76 citations