The x-ray excited Auger electron spectrum of NO and potential curves and photodissociation of the NO2+ ion

Abstract

A study of the NO2+ ion by means of Auger spectroscopy, fast ion beam laser spectroscopy and ab initio calculations is reported. The photon induced Auger spectrum of NO was recorded. Potential curves for a number of electronic states of NO2+ were calculated by the complete active space SCF method in order to facilitate an analysis of the Auger spectrum. A photoabsorption spectrum of NO2+ was observed by means of photofragment kinetic energy spectroscopy and assigned to the A 2Π←X 2Σ+ transition. The two different experimental methods both give a value of 38.6 eV for the appearance energy of NO2+, which is entirely consistent with recent photoionization and double charge transfer results.