Nonlinear-optical response in polythiophene films using four-wave mixing techniques

Abstract

We report measurement of X(3) in polythiophene and a homologous series of polycondensed thiophene-based polymers above and below the absorption edge using the folded-boxcar four-wave mixing technique. Above gap the nonlinear coefficient X(3) was found to be one of the largest and fastest in a polymer.