Concepedia

Direct Demonstration of Enhanced Diffusion in Mesoporous ZSM-5 Zeolite Obtained via Controlled Desilication

Johan C. Groen, Weidong Zhu, Sander Brouwer, Steven J. Huynink, Freek Kapteijn, Jacob A. Moulijn, Javier Pérez‐Ramírez

Journal of the American Chemical Society · 2006 · 698 citations · 26 references

DOI

Concepts

Abstract

A 2 orders of magnitude gas transport improvement in a medium pore ZSM-5 zeolite has been achieved upon introduction of intracrystalline mesoporosity in gradient-free crystals by desilication post-treatment in alkaline medium.

References

26

Diffusion in Zeolites and Other Microporous Solids.

R. Mann · Chemical Engineering Science · 1993 · 1.4K citations

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Generation, Characterization, and Impact of Mesopores in Zeolite Catalysts

Sander van Donk, Andries H. Janssen, Johannes H. Bitter et al. · Catalysis Reviews · 2003 · 843 citations · Full text

, , +17

Desilication: on the controlled generation of mesoporosity in MFI zeolites

Johan C. Groen, Jacob A. Moulijn, Javier Pérez‐Ramírez · Journal of Materials Chemistry · 2006 · 571 citations

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A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst

Avelino Corma, María J. Díaz‐Cabañas, Joaquı́n Martı́nez-Triguero et al. · Nature · 2002 · 546 citations

, , +15

Mechanism of Hierarchical Porosity Development in MFI Zeolites by Desilication: The Role of Aluminium as a Pore‐Directing Agent

Johan C. Groen, L.A.A. Peffer, Jacob A. Moulijn et al. · Chemistry - A European Journal · 2005 · 537 citations

, , +17