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197Au-Mössbauer Spectroscopic Studies of Monomeric and Trimeric Gold(I) Azolates

Motomi Katada, Kumiko Sato, Yoshio Uchida, Seiichiro Iijima, Hirotoshi Sano, Hongyang Wei, Hiroshi Sakai, Yutaka Maeda

Bulletin of the Chemical Society of Japan · 1983 · 13 citations · 1 references

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Abstract

Abstract The identical chemical state of three gold atoms in trimeric gold(I) azolates and the Au(I)–Au(III) mixed-valence state in their iodine adducts, Au3(az)3I2, were confirmed by means of 197Au-Mössbauer spectroscopy.

References

1

Metal derivatives of azoles. 3. The pyrazolato anion (and homologs) as a mono- or bidentate ligand: preparation and reactivity of tri-, bi-, and mononuclear gold(I) derivatives

Giovanni Minghetti, Guido Banditelli, Flavio Bonati · Inorganic Chemistry · 1979 · 93 citations

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