Journal of Geophysical Research Atmospheres · 1988 · 54 citations · 11 references
Natural SciencesChemistryPhysicsAnalytical ChemistryAtomic PhysicsSpectroscopyAtomic Energy LevelsCross Section DataElectron Cross SectionsElectron Excitation ProcessesExcitation Cross Sections
A new apparatus designed specifically for the study of electron scattering from unstable species at very low incident energies has been constructed and put into operation. Remeasurement of the O I ³P → ³S 0 (1304 Å) differential and integral cross sections (DCS and ICS) at energies below 30 eV has provided new values for the DCS and ICS for this cross section as well as for the ³P → ³D 0 (989 Å) transition. These new values replace the cross sections reported by Vaughan and Doering (1987) which were measured in the original apparatus designed for high incident energy work. The two sets of measurements agree at incident energies 30 eV and above. However, the new values for the ³P → ³S 0 transition at 20 and 16.5eV are larger than the previous measurements by a factor of 2 to 3. Extension of the work on this transition down to 13.87 eV shows that the cross section remains large to within a few eV of threshold, in agreement with the theoretical predictions of Rountree and Henry (1972) and Smith (1976). Similar behavior is observed for the ³P → ³D 0 (989 Å) transition down to 20 eV.
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