The Journal of Chemical Physics · 1971 · 100 citations · 15 references
Natural SciencesChemistryPhysicsChemical KineticsMolecular PhysicsSpectroscopyEmission SpectroscopyFluorescence SpectroscopyMolecular SpectroscopyOptical SpectroscopyPhotochemistryTime-resolved SpectroscopyFluorescence LifetimeFluorescence Lifetime MeasurementsNanosecond SpectroscopySolvent EffectsSpectral ShiftsTime-resolved Emission SpectroscopyTime-resolved Fluorescence SpectroscopyTransient Fluorescence Spectroscopy
Nanosecond time-resolved emission spectroscopy and fluorescence lifetime measurements are reported for 1-anilino-8-naphthalene sulfonate. Time-dependent spectral shifts are observed that are interpreted in terms of dipole reorientation of the solvent around the electronically excited molecule. Both the radiative and nonradiative transitions probabilities are observed to be strongly solvent dependent.
15