Concepedia

Enantioselective Synthesis of <i>syn</i>- and <i>anti-</i>1,3-Diols via Allyltitanation of Unprotected β-Hydroxyaldehydes

Samir BouzBouz, Janine Cossy

Organic Letters · 2000 · 45 citations · 25 references

DOI

Concepts

Abstract

[reaction: see text] syn or anti-1,3-Diols units were synthesized with excellent diastereomeric excess from unprotected chiral beta-hydroxyaldehydes by using an enantioselective allyltitanation.

References

25

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, , +6

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1,3- diastereoselective reduction of β-hydroxyketones utilizing alkoxydialkylboranes

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Samarium-catalyzed intramolecular Tishchenko reduction of .beta.-hydroxy ketones. A stereoselective approach to the synthesis of differentiated anti 1,3-diol monoesters

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, , +8

Stereoselective reduction of β hydroxyketones to 1,3-diols highly selective 1,3-asymmetric induction via boron chelates

Koichi Narasaka, Fong-Chang Pai · Tetrahedron · 1984 · 339 citations

, , +7