Journal of the Chemical Society A Inorganic Physical Theoretical · 1969 · 31 citations · 0 references
Natural SciencesChemistryPhysicsInorganic ChemistryOrganometallic ChemistrySpectroscopyCoordination ChemistryElectron Paramagnetic ResonanceElectron Spin Resonance SpectroscopyInorganic SpectroscopyMetal-ligand BondingTransition Metal ComplexesElectronic Spectra Of Transition Metal ComplexesElectronic Structure Of Metal ComplexesMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesManganese ChemistryParamagnetic ComplexesSpectroscopy Of Transition Metal Complexes
E.s.r. spectra of the complexes MnL2Cl2(L = Ph3PO, Ph3AsO), MnL2Br2(L = Ph3PO, Ph3AsO, 3-methylisoquinoline, or quinoline), Mn(Ph3PO)2I2, and Mn(Ph3AsO)2(NCS)2 are reported at X-band and at Q-band frequencies, together with those of some of the complexes diluted in the corresponding zinc compound. The spectra are interpreted by comparison with calculated spectra, and values of the distortion parameters D and λ(=E/D) have been deduced.