Physical Review · 1965 · 50 citations · 7 references
Natural SciencesChemistryPhysicsMolecular PhysicsOpticsSpectroscopyAbsorption SpectroscopyAtomic Absorption SpectroscopyAtomic SpectraOptical SpectroscopyAbsorption SpectraOptical Absorption SpectraPhotoabsorption SpectraPhotoelectric Effect
The continuous atomic and molecular cross sections of potassium vapor have been measured using photoelectric techniques from the $4{s}^{2}S\ensuremath{\rightarrow}n{p}^{2}{P}^{0}$ series limit at 2856 to 1150 \AA{}. The bandwidth of the monochromator was 0.75 \AA{} and values of the cross sections were obtained at 2-\AA{} intervals. The value obtained for the atomic absorption cross section at the series limit was 0.010\ifmmode\pm\else\textpm\fi{}0.003 Mb or 0.012\ifmmode\pm\else\textpm\fi{}0.003 Mb, depending on which vapor-pressure formula was used in the analysis of the results. A minimum of 0.002\ifmmode\pm\else\textpm\fi{}0.002 Mb was observed between 2730 and 2600 \AA{}. This latter result disagrees with previous experimental results but is in agreement with theoretical predictions.
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