Equilibrium Phase Compositions of CO2/Crude Oil Mixtures—Part 2: Comparison of Continuous Multiple-Contact and Slim-Tube Displacement Tests

Abstract

Abstract Results of phase composition and density measurements for CO2/crude-oil mixtures at 32°C and four pressures are reported for a system in which liquid/liquid and liquid/liquid/vapor phase separations occur. The experiments demonstrate that a CO2-rich liquid phase can contain as much as 30 wt% hydrocarbons and show that a CO2-rich vapor phase at the same conditions extracts hydrocarbons less efficiently. Pseudoternary phase diagrams are presented that summarize the results of the detailed phase composition measurements. Results of slim-tube displacements at the same four pressures are also given. They indicate that displacement is efficient when the pressure is high enough that a liquid CO2-rich phase appears. Predictions of the performance of the slim-tube displacements based entirely on the experimental measurements of phase compositions and densities are obtained using a simple one-dimensional (1D) simulator. The simulation results clarify the roles of phase behavior and volume change on mixing in the siim-tube tests. Finally, the advantages and limitations of the slim-tube and continuous multiple-contact (CMC) tests are compared. We conclude that the CMC experiment yields more information useful for prediction of the performance of a CO2 flood.