The Journal of Chemical Physics · 1966 · 26 citations · 6 references
Natural SciencesChemistryPhysicsCondensed Matter PhysicsSolid-state ChemistrySpectroscopyCrystal Field TheoryMagnetic Properties Of SolidsMagnetism In SolidsMagnetism Of Inorganic CompoundsZeeman EffectMagnetic Dipole InteractionNuclear Magnetic Dipole TransitionsOscillator StrengthsZeeman Effect In Excited StatesZeeman Effect In SpectroscopyZeeman Effect MeasurementsZeeman Spectroscopy
The oscillator strengths of several magnetic-dipole transitions for U4+ in Cs2UCl6 have been measured, and compared with calculated values using the eigenfunctions previously determined. The Zeeman effect of the only line showing a splitting in a 30-kg field in the photographic region of the spectrum was observed and g∥ and g⊥ were compared with theoretical values. The second-degree term of the D3d crystalline-field distortion from the large cubic field was obtained.
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