Journal of the Chemical Society A Inorganic Physical Theoretical · 1967 · 48 citations · 0 references
Natural SciencesChemistryInorganic ChemistrySpectroscopic AnalysisSpectroscopyCoordination ChemistryInorganic SpectroscopyMetal-ligand BondingSpectral InterpretationTransition Metal ComplexesVibrational StructureElectronic Spectra Of Transition Metal ComplexesOctahedral ComplexesOctahedral CoordinationVibrational ModesVibrational Spectroscopy Of Metal-ligand Bonds
Vibrational spectra of the following ions are reported: InCl63–, TlCl63–, PbCl64–, SbCl63–, BiCl63–, SeCl62–, TeCl62–, SbCl52–. It is suggested that ν3 for the octahedral “inert pair ions” may be anomalously broad. In species such as Cs2SbCl6 the presence of SbIII and SbV is observed and the relative intensities of the bands due to the individual complex ions are briefly discussed.