New Journal of Chemistry · 2012 · 24 citations · 31 references
Natural SciencesChemistryAnalytical ChemistryInorganic ChemistrySpectroscopyChemical Probe DiscoveryFluorescence SpectroscopyInfrared SpectroscopyInorganic SpectroscopyOptical SpectroscopyPhotophysics Of Fluorescent ProbesAqueous Reaction MediaComplexation ChemistryEmission SpectraFluorescence ProbesFluorescent Chemical ProbesFluorescent Probe DesignFluorescent ProbesIsomerization Processes
A new type of fluorescent probe (L) for Fe3+ based on CN isomerization was synthesized. It shows fluorescence enhancement (turn-on) response for Fe3+ in aqueous media (v(CH3CN) : v(H2O) = 1 : 9). The complexation mode and the corresponding fluorescent enhancement mechanism were elucidated by IR spectra, transient spectra, Job plot, and DFT calculations.
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